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遷移金属触媒を用いた新規反応の開発
ヘテロ環合成法の開発

原著論文

1. Wakayama, F.; Ito, R.; Park, K.; Ishida, M.; Yamada, Y. Ichihara, S.; Takada, H.; Nakamura, S.; Kato, A.; Yamada, T.; Sajiki, H.*; Monguchi, Y.* Esterification or thioesterification of carboxylic acids with alcohols or thiols using amphipathic monolith-SO3H resin. Bull. Chem. Soc. Jpn., 94, 2702–2710 (2021).
2. Ichikawa, T.; Matsuo, T.; Tachikawa, T.; Teranishi, W.; Yamada, T.; Sawama, Y.; Monguchi, Y.; Sajiki, H.* Microwave-mediated continuous hydrogen abstraction reaction from 2-PrOH catalyzed by platinum on carbon bead. Catalysts, 9, 655 (2019).
3. Yamada, T.; Kobayashi, Y.; Ito, N.; Ichikawa, T.; Park, K.; Kunishima, K.; Ueda, S.; Mizuno, M.; Adachi, T.; Sawama, Y.; Monguchi, Y.; Sajiki, H.* Polyethyleneimine-modified polymer as an efficient palladium scavenger and effective catalyst support for a functional heterogeneous palladium catalyst. ACS Omega, 46, 10243–10251 (2019).
4. Ichikawa, T.; Matsuo, T.; Tachikawa, T.; Yamada, T.; Yoshimura, T.; Yoshimura, M.; Takagi, Y.; Sawama, Y.; Sugiyama, J.-i.; Monguchi, Y.; Sajiki, H.* Microwave-mediated site-selective heating of spherical-carbon-bead-supported platinum for the continuous, efficient catalytic dehydrogenative aromatization of saturated cyclic hydrocarbons. ACS Sustain. Chem. Eng., 7, 3052–3061 (2019).
5. Yamada, T.; Matsuo, T.; Ogawa, A.; Ichikawa, T.; Kobayashi, Y.; Masuda, H.; Miyamoto, R.; Bai, H.; Meguro, K.; Sawama, Y.; Monguchi, Y.; Sajiki, H.* Application of thiol-modified dual-pore silica beads as practical scavenger of leached palladium Catalyst in C–C coupling reaction. Org. Process Res. Dev., 23, 462–469 (2019).
6. Ichikawa, T.; Matsuo, T.; Tachikawa, T.; Sawama, Y.; Monguchi, Y.; Sajiki, H.* Heterogeneous copper–catalyzed synthesis of S–arylated 2-aminothiophenols via ring opening of benzothiazoles and C–S coupling using aryl halides. Heterocycles, 97, 793–805 (2018).
7. Yoshimura, M.*; Komatsu, A.; Niimura, M.; Takagi, Y.; Takahashi, T.; Ueda, S.; Ichikawa, T.; Kobayashi, Y.; Okami, H.; Hattori, T.; Sawama, Y.; Monguchi, Y.*; Sajiki, H.* Selective synthesis of primary amines from nitriles under hydrogenation conditions. Adv. Synth. Catal., 360, 1726–1732 (2018).
8. Ichikawa, T.; Mizuno, M.; Ueda, S.; Ohneda, N.; Odajima, H.; Sawama, Y.; Monguchi, Y.*; Sajiki, H.* A practical method for heterogeneously-catalyzed Mizoroki–Heck reaction: flow system with adjustment of microwave resonance as an energy source. Tetrahedron, 74, 1810–1816 (2018).
9. Monguchi, Y.*; Mizuno, M.; Ichikawa, T.; Fujita, Y.; Murakami, E.; Hattori, T.; Maegawa, T.; Sawama, Y.; Sajiki, H.* Catalyst-dependent selective hydrogenation of nitriles: Selective synthesis of tertiary and secondary amines. J. Org. Chem., 82, 10939–10944 (2017).
10. Hattori, T.; Okami, H.; Ichikawa, T.; Mori, S.; Sawama, Y.; Monguchi, Y.*; Sajiki, H.* Ruthenium on carbon catalysed carbon-carbon cleavage of aryl alkyl ketones and aliphatic aldehydes in aqueous media. Adv. Synth. Catal., 359, 3490–3495 (2017).
11. Ichikawa, T.; Netsu, M.; Mizuno, M.; Mizusaki, T.; Takagi, Y.; Sawama, Y.; Monguchi, Y.*; Sajiki, H.* Development of a unique heterogeneous palladium catalyst for Suzuki–Miyaura reaction using (hetero)aryl chlorides and chemoselective hydrogenation. Adv. Synth. Catal., 359, 2269–2279 (2017).
12. 横山さゆり,吉武毅人,「薬学部1年生の国際保健医療協力に対する意識調査」Jpn.J.Pharm.Health Care Sci.,35(11),782-790 (2009)

総説

1. Monguchi, Y. Nitriles for the production of various amines. Science, 376 (6600), 1382–1383 (2022).
2. Monguchi, Y.*; Ichikawa, T.; Yamada, T.; Sawama, Y.; Sajiki, H.* Continuous-flow Suzuki–Miyaura and Mizoroki–Heck reactions under microwave heating conditions. Chem. Rec., 19, 3–14 (2019).
3. Monguchi, Y.*; Ichikawa, T. Sajiki, H.* Recent development of palladium-supported catalysts for chemoselective hydrogenation. Chem. Pharm. Bull. (Current Topics), 65, 2–9 (2017).
4. Monguchi, Y.*; Sawama, Y.; Sajiki, H.* Synthesis of triazole, indole, and five or six-membered saturated heterocyclic compounds. Heterocycles, 91, 239–264 (2015).

〒815-8511 福岡市南区玉川町22-1
第一薬科大学　薬品化学分野
TEL. 092-541-0161
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横山　さゆり　(内線394)